Aug. 06, 2024
Lithium Nickel Manganese Cobalt (Li-NMC) and Lithium Ferrous Phosphate (LiFePO4 or LFP) sound like two batteries that should be more or less the same. After all, they both have lithium in them.
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However, there is a vast difference between these two battery technologies, enough to make you think for a while before investing in one of them.
No doubt lithium-based battery technology is a significantly better choice than traditional lead acid batteries. However, when the decision lies between two lithium batteries like Lithium MNC and LiFePO4, which one would you choose?
This article gives an in-depth comparison between these two battery technologies competing for your money. After reading the information provided here, you will know how each battery performs under various operating parameters and which will suit you the most.
What is the Difference Between Lithium NMC and LFP Batteries?
These new technologies, Lithium NMC and Lithium Iron Phosphate are both types of lithium batteries, but the working principle of each differs.
Li-NMC, LMNC, or NMC batteries use Lithium Nickel Manganese Cobalt Oxide (LiNiMnCoO2) as cathode material.
Lithium-ion batteries differ from other lithium batteries, such as LFP batteries, due to the properties of the cathode materials.
LFP or LiFePO4 batteries are lithium-based and use Lithium Ferrous Phosphate as the cathode material.
NMC and LFP battery chemistries have many common factors. For one, both are lithium-ion batteries, which means that the flow of lithium ions generates the power stored in each battery.
Although both use different types of cathode materials, the anode is always carbon-based, usually graphite. The rest of the construction of the battery pack is also very similar.
How Do LiFePO4 Batteries and Lithium NMC Batteries Compare?
Lets explore the various factors that affect how each battery performs to understand the differences between these two technologies:
The energy density of a battery pack is also referred to as embodied energy. Energy density is the amount of energy a battery holds relative to its weight. A higher energy density is preferred because a smaller high-power battery can provide a higher output.
Energy density is calculated by the formula:
Energy Density = Battery Watt Hours ÷ Battery Weight
The best thing about NMC batteries is their high energy density. Generally, NMC battery energy is 150-200 Wh/Kg.
LFP batteries also have a high energy density, 100-150 Wh/Kg. They are a better choice than some, but not the best.
Verdict: NMC batteries have better energy density than LFP batteries. This makes NMC batteries better for applications that need small batteries with moderate power capacity.
Cycle life is the number of charge-discharge-charge cycles a battery can sustain without any performance degradation. A single charge cycle is when the battery is discharged from its fully charged state and is then charged again.
A longer cycle life indicates a better battery lifespan. It is an important consideration as it directly reflects the value for money factor.
An NMC battery has an expected cycle life of about - cycles. It can provide full power for about three to four years but then suffers fast degradation.
An LFP battery has a typical cycle life of about cycles. It can perform optimally for seven to ten years, followed by slow degradation. In fact, high-quality Eco Tree Lithium LFP batteries come with a 6-year warranty.
Verdict: LFP technology produces a significantly better battery cycle life than NMC batteries and can last twice as long.
The depth of discharge (DoD) is the level to which a battery can be discharged without damaging it. For example, if a battery has a DoD of 80%, battery health will deteriorate if discharged below 20%.
Therefore, a higher DoD indicates a better operational range of a battery.
NMC batteries, like other Lithium-ion batteries, have a DoD in the range of 80% to 90%. This is much better compared to lead-acid batteries (50%).
The depth of discharge for a typical LFP battery is an astonishing 100%. This means you can use all the stored power in the battery without any worry about damaging it.
Verdict: Both batteries have a good depth of discharge, but LFP batteries are the winner. A 100% depth of discharge also reduces the oversight required by the battery owner.
The cost per KWh is the price paid for the battery divided by the total kilowatt hours (KWh) it can provide.
For example, if you buy a 100 Ah battery for £100 and it can provide watt-hours of power, then the cost per KWh is £0.10.
The cost per KWh can be an important consideration for people with budget constraints.
NMC batteries are expensive because of the materials used in the battery. NMC batteries require Nickel, Manganese, and Cobalt in considerable quantity for the cathode material.
LFP batteries are cheaper than NMC batteries because they use iron and phosphate as cathode materials, which are abundant and cheap.
Verdict: LFP batteries have a significant edge over NMC batteries when considering the cost per KWh of each battery type. Couple this with the longer lifespan LFP technology offers, and LFP batteries are clearly the winner, offering the best value for money.
Since a battery operates at high voltage and can reach a high temperature, safety is vital. Battery safety includes both high thermal stability and chemical stability.
NMC batteries have stable chemistry. However, the battery chemistry results in the release of Oxygen. Therefore, improper construction or inappropriate battery use can make it catch fire or explode.
LFP batteries have stable chemistry and can handle high temperatures quite well. They dont overheat, so there is no need to worry about the temperature threshold at all.
Additionally, there is no oxygen release from LFP batteries. So there is no concern about flammability even at a high temperature.
Verdict: LFP batteries win again on safety criteria. One thing to note is that all lithium batteries have high safety compared to lead-acid batteries.
Even when a battery is not supplying power to a load, the internal chemical reactions cause it to lose some of the power stored. The self-discharge rate of a battery is the percentage of the rated capacity that gets discharged when not connected to a load.
NMC batteries have a self-discharge rate of 4% per month. This means that a fully charged NMC battery in proper storage conditions will retain about 96% of its charge after a month.
LFP batteries have a self-discharge rate of just 3% per month. Therefore, a fully charged LFP battery in proper battery storage conditions will retain 97% of its charge after a month.
Verdict: These two technologies have admirable self-discharge rates, with LFP batteries offering slightly better performance.
Although high temperatures are dangerous for battery health, low temperatures also pose a risk to battery operation. At freezing temperatures, a battery often ceases to function since the necessary chemical reactions inside it cant continue.
A Lithium Nickel Manganese Cobalt Oxide battery has poor performance in sub-zero temperatures. It can stop functioning and wont start again until you find a way to raise the batterys temperature.
LFP Battery
Lithium-ion chemistry in batteries is affected by cold temperatures, similar to an NMC battery. However, high-quality Lithium Iron Phosphate batteries, like the ones provided by Eco Tree Lithium, come with a Battery Management System (BMS).
The battery management system regulates all vital parameters of the battery for optimal operation. One of its advantages is that it can heat the battery in low temperatures, leading to uninterrupted operation.
Verdict: The performance of all batteries in the lithium-ion battery family is poor at sub-zero temperatures. However, the BMS of LFP batteries makes them a better choice for such conditions.
Thermal runaway happens when the battery chemistry becomes uncontrollable at a high temperature. It is not only dangerous for battery operation but also for the safety of surrounding property and people.
The lithium-ion battery family is known for thermal runaway. In fact, thermal runaway is the exclusive property of this battery class. At high temperatures, overheating occurs, which can cause them to explode.
Since LFP batteries do not overheat, there is no thermal runaway. Even at high temperatures, the Lithium Iron Phosphate compound is stable, which eliminates the possibility of thermal runaway.
Verdict: Comparing the risk of thermal runaway for NMC vs LFP, LFP is the clear winner, as it eliminates any concern about thermal runaway in the battery.
More and more people and manufacturers are moving towards green initiatives that do not have a negative environmental impact. The environmental impact of battery manufacture and use are important factors to consider.
NMC batteries use cobalt as the cathode material, which poses a considerable environmental risk. Using cobalt cathode materials creates toxic fumes throughout the batterys lifetime and even after disposal.
LFP batteries are cobalt-free, so there is no negative environmental impact at all. In fact, LFP batteries are one of the most environmentally friendly battery technologies.
Verdict: An LFP battery is the best choice for people who want a green battery. Additionally, the longer lifespan of LFP batteries means fewer battery changes are needed.
Comparing Lithium NMC vs LiFePO4 in terms of power and voltage delivery: how do these two battery technologies compare?
Lithium NMC batteries offer stable power delivery, with little variation in voltage output even as the battery discharges. This makes them ideal for applications where consistent power delivery is crucial, such as medical devices or electronic cigarettes.
In terms of voltage delivery, lithium NMC outperforms LFP. The average voltage output of a lithium NMC battery is about 3.7V, compared to 3.2V for a LiFePO4 battery. This higher voltage makes lithium NMC batteries better suited to high-power output applications, such as electric vehicles.
LFP batteries also offer stable power delivery, but their voltage output may drop rapidly as the battery discharges. However, this decrease in voltage is much less pronounced than with other types of Lithium-ion batteries, making LiFePO4 a good choice for applications where stable power delivery is important.
Verdict: LiFePO4 lithium iron phosphate batteries are the clear winner on stability. However, lithium NMC batteries may be a better option if you need a battery with high power output.
Choosing Between LiFePO4 and Li-NMC Battery
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Overall, considering all the factors above, LFP batteries are the better choice by a significant margin. However, which battery will be better for you can vary depending on what you require from a battery power supply.
For applications where space is the primary concern, NMC batteries are beneficial because of their high energy density. Therefore, NMC batteries are the better choice for applications such as electronics, mobile phones, laptops, etc.
In the case of applications that demand high performance, better battery storage, long cycle life, thermal stability, or higher quality, LFP batteries are the best option. LFP batteries are used extensively in electric vehicles, solar systems, leisure vehicles such as caravans, motorhomes, boats, and similar applications.
If you have decided to buy a Lithium Iron Phosphate battery, Eco Tree Lithium is the best choice.
Eco Tree Lithium manufactures some of the leading LFP batteries in the UK, providing unparalleled performance at the best price possible.
These Lithium Iron LiFePO4 Batteries excel in performance, features, and build quality. Eco Tree Lithium batteries come with a 6-year warranty on any battery you buy.
Key Takeaways
Buying a new battery can be a tough decision since there are so many options on the market today.
Of the countless alternatives, NMC batteries and LFP batteries are two of the top performers out there. Now that you have read this article, you can make better decisions about which type of battery will be the right fit for you.
Frequently Asked Questions (FAQs)
Here are the answers to some frequent questions that people have regarding these common lithium battery types.
Yes. An LFP battery pack is a better overall choice than an NMC battery. Not only does it represent higher value for money, but it also has greater stability, a longer lifespan, and is environment-friendly.
LFP is considerably cheaper than NMC because an NMC battery pack contains scarce elements like Cobalt, which are very expensive.
Lithium-ion solar batteries are the most popular option for home energy storage because they last long, require little maintenance, and dont take up as much space as other battery types. Lithium solar batteries typically cost between $12,000 and $20,000 to install.
When paired with solar panels, excess solar energy can be stored in the battery and used later, like at night or during a power outage. Depending on the area, lithium ion batteries can even help save extra money on electricity bills.
Lets take a closer look at what you need to know about lithium-ion batteries before getting one installed.
Lithium batteries are rechargeable energy storage solutions that can be installed alone or paired with a solar energy system to store excess power.
Standalone lithium-ion batteries can be charged directly from the grid to provide homeowners with backup power in case of a power outage. They can also be used to avoid paying for peak electricity rates, by charging with grid power when electricity is cheap and discharging when its expensive.
Pairing a battery with solar will give you the most bang for your buck, especially if you dont have access to net metering. The lithium battery can recharge with excess solar energy that is generated by your panels, so you can run your home entirely with solar even when the sun isnt shining.
Lithium-ion solar batteries dont come cheap, with installations ranging from $10,000 for a simple single-battery solution, to well over $30,000 for whole-home backup. This is significantly higher than that of installing lead-acid batteries, which typically run between $5,000 and $15,000.
Despite the price difference, people still tend to choose lithium-ion batteries over lead-acid because of increased performance and fewer maintenance concerns. The total cost of a solar battery installation depends on the battery brand you choose, the features it has, how many batteries you need, and labor costs.
Battery incentives can help lower costs. There are a number of solar battery incentives that help lower installation costs. The biggest is the federal tax credit, which is equal to 30% of the total costs of qualifying battery installations. There are a number of local battery incentives and rebates, pilot programs like Green Mountain Power's battery lease, and things like virtual power plant programs are becoming more popular, as well.
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High depth of discharge
Long lifespan
High energy density
High efficiency
Little maintenance
High cost
Thermal runaway
Lithium-ion batteries are the most popular option for homeowners looking for battery storage for good reason. Here are some of the benefits of lithium-ion home batteries:
The DoD of a battery is the amount of the stored energy in the battery that has been used compared to the total capacity of the battery. Most batteries come with a recommended DoD to maintain their health.
Lithium-ion solar batteries are deep cycle batteries, so they have DoDs around 95%. Compare this to lithium ion batteries, which have DoDs closer to 50%. Basically, this means you can use more of the energy thats stored in a lithium-ion battery and you dont have to charge it as often.
Because lithium ion batteries have a high DoD and dont need to be charged and recharged as often, they have a long lifespan.
Most lithium-ion solar batteries have a minimum warrantied lifespan of around 10 years, or a cycle life of 10,000 cycles - whichever comes first. Lead acid batteries, on the other hand, only have warrantied lifespans of around 5 years.
The energy density of a battery is how much power the battery can hold relative to the physical size of the battery.
Lithium-ion batteries can store more power without taking up as much space as lead-acid batteries, which is great for homes where space is limited.
Lithium-ion batteries have a higher round-trip efficiency rating than other types of solar batteries on the market.
Efficiency refers to the amount of usable energy you get out of your battery compared to how much energy it took to store it. Lithium-ion batteries have efficiencies between 90 and 95%.
Not having to worry about regular maintenance is one of those advantages that you just cant put a price on. Lithium-ion batteries require little to no regular maintenance - just make sure theyre clear of debris and. Some lead-acid batteries, on the other hand, require frequent off-gassing.
Although lithium-ion batteries have numerous benefits, there are still some draw backs.
Lithium-ion batteries tend to be the most expensive battery storage option, especially when compared to lead-acid batteries.
The good news is that solar battery systems qualify for incentives like the federal tax credit, which helps make lithium-ion batteries more affordable.
Its also important to remember that while lead-acid batteries may be cheaper upfront - they have to be replaced more often, increasing your overall storage costs.
Lithium-ion batteries run a higher risk of thermal runaway, AKA overheating and catching on fire. While the risk is technically there, the chances of this happening with a properly installed lithium-ion battery is slim to none.
There are many lithium-ion solar batteries on the market. Some of the best solar battery brands include Enphase, Panasonic, and Tesla.
The following table outlines some other popular lithium-ion solar batteries on the market:
At $682 per kWh of storage, the Tesla Powerwall costs much less than most lithium-ion battery options. But, one of the other batteries on the market may better fit your needs.
There are two main types of lithium-ion batteries used for home storage: nickel manganese cobalt (NMC) and lithium iron phosphate (LFP).
An NMC battery is a type of lithium-ion battery that has a cathod made of a combination of nickel manganese and cobalt. When people say lithium-ion batteries theyre often referring to NMC batteries. These batteries are what shot lithium-ion to the mainstream, with better performance than that of their lead-acid competitors. The Generac PWRcell, LG RESU Prime, and Tesla Powerwall 2 are NMC batteries.
LFP battery cathodes are made of lithium irone phosphate (LiFePO4) and are still considered lithium-ion batteries. The iron and phosphate used to make the cathode are more abundant and less expensive than some of the materials used in NMC batteries - mainly cobalt. The Enphase IQ, Panasonic EverVolt, and Powerwall 3 use LFP technology.
More battery manufacturers have been switching to LFP batteries because they dont contain expensive, toxic cobalt. LFP batteries are easier to recycle, a little bit cheaper, longer lasting, and ,most notably, safer. Aside from having fewer toxic metals, LFP batteries are better at handling temperature fluctuations and are even less likely to experience thermal runaway than their NMC competitors.
Batteries are recycled by being shredded and mixing all of their components. Once all of the metals are mixed into a powder, they need to be separated by either being liquified or dissolved in acid so that the desired metal can be retrieved.
Since the process of recycling batteries is still in the early stages, the United States has suggested an enhancement to the Defense Production Act. The goal is to put money towards securing the metals we need for a clean energy transition while also researching and investing in recycling lithium-ion batteries.
Alternatively, instead of shredding old batteries, sometimes batteries within an EV can be reused. Lithium-ion batteries have a very long lifespan, and while they will lose their ability to power a car, they can still be used for less intense energy storage needs, like backup power.
Currently, when you replace technology such as your EV or storage battery, recycling the old one is a chore. You can find certified electronics recyclers through the EPA website. Alternatively, some manufacturers like Tesla will take back their lithium-ion batteries at the end of their life to be recycled.
At this stage, current recycling methods are not sophisticated enough to extract most of the key metals that can be reused in a way that is more cost-effective than mining.
It is cheaper to mine most metals found within a lithium-ion battery than recycle them. Perhaps ironically, cheap lithium mining is one of the many reasons we can invest heavily in batteries. Unfortunately, if we build cheap lithium batteries that are not recycled, we will end up with landfills full of electronic waste.
While recycling batteries may require some extra work and additional cost, the metals within the batteries are durable and usable. Recycling needs to become economical to reduce our dependency on freshly-mined lithium.
Since lithium mining emits a high amount of CO2, using lithium and other metals from recycled batteries is a more environmental and sustainable alternative.
Additionally, a potential shortage of metals that are used in batteries is looming. Discovering a way to reuse all the metals within old batteries will help meet supply needs.
Lithium-ion solar batteries are the best solar energy system for everyday residential use because they take up little space while storing a substantial amount of energy. They last longer and provide more usable energy than lead-acid batteries, plus they require little maintenance.
However, sometimes a lead-acid battery might be the better choice. If youre only using a solar battery for backup storage and not daily use, or if youre looking for storage for an off-grid solar project, lead-acid batteries will get the job done and wont break the bank.
However, if were being totally honest, most homeowners probably dont need a battery at all. Solar batteries do provide numerous benefits, but their substantial upfront costs means they dont quite make sense as a financial investment in most cases. It depends largely on local policy, utility rates, battery incentive programs. and how frequently you expertience power outages.
The best way to figure out if a solar battery is worth if for you is by speaking with multiple solar installers. Solar companies can give you an idea of how much a lithium-ion battery can save you (if anything) and if its something you should consider for your home.
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