Apr. 14, 2025
Nanofiltration refers to a specialty-membrane process that rejects dissolved solutes in the approximate size range of 1 nanometer (10 Angstroms) — hence the term “nanofiltration.”
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With respect to the size and weight of solutes that nanofiltration membranes reject, NF operates in the realm between reverse osmosis (RO) and ultrafiltration (UF) : Organic molecules with molecular weights greater than 200 – 400 are rejected. Nanofiltration membranes can effectively reject, among other contaminants:
It also rejects certain soluble salts. Specifically, NF rejects dissolved salts in the range of 20 – 98 percent. Salts which have monovalent anions (e.g., sodium chloride or calcium chloride) have rejections of 20 – 80 percent, whereas salts with divalent anions (e.g., magnesium sulfate) have higher rejections of 90 – 98 percent. Transmembrane pressures are typically 50 – 225 psi (3.5 – 16 bar).
The ideal nanofiltration membrane has a very high water permeability, but the ideal permeability of solutes might be near zero or some higher value, depending on the solute and application. For example, an application may require near-zero permeability for pesticides and 50 percent permeability for calcium ions.
Typical applications of nanofiltration membrane systems include:
Like reverse osmosis membranes, nanofiltration membranes are used in separation systems employing applied pressure to effectively overcome the system’s osmotic pressure, reversing the flow of a solvent across a semipermeable membrane from an area of higher solute concentration to an area of lower concentration. This “reversed” flow, and the degree of permeability of the nanofiltration membrane, result in solutes too large to pass through the membrane remaining on the higher-concentration side of the membrane, while purer water that contains desired or acceptable solutes flows through.
Nanofiltration membranes are similar to RO membranes in another way: They are used in crossflow configurations. Crossflow helps to minimize fouling, or the accumulation of solutes that cannot pass through the semipermeable membrane against the membrane. Very simply stated, in crossflow a pressurized flow of feedwater forces lower-concentration water through the NF membrane, while the now-isolated flow of higher-concentration water moves across the surface of the membrane, carrying away the rejected salts and other impurities. The purified water is called the permeate, while the higher-concentration water is called the concentrate or reject.
In , theNational Resources Defense Council identified more than 80,000 violations of the Safe Water Drinking Act in the U.S. These included failures to meet health standards plus monitoring and reporting shortfalls.
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The unfortunate reality is that water quality in homes around the country is inconsistent. And while most U.S. homes have tap water that meets EPA safety guidelines, that doesn't mean your water is germ-free.
This is why theCDC recommends filtration as an extra step to ensure cleaner, safer water in your home. Acting on that recommendation can be challenging, though. Start researching filters and you'll see why. There are different methods of filtration, such as microfiltration, ultrafiltration, nanofiltration, and reverse osmosis. It can feel like you need a science degree to understand which is best.
This guide should clear up the confusion. Let's look at how filtration works generally, the differences between filtration methods, and which option is best for your home.
Despite their complicated names, ultrafiltration, nanofiltration, and reverse osmosis are straightforward concepts. All three methods clean water by pushing it through a membrane with tiny holes, which are called pores. Pores are measured in micrometers, abbreviated as um. (One micrometer is one-millionth of a meter.) As water passes through the pores, substances in the water get stuck in the membrane.
Pore size is the primary difference among microfiltration, ultrafiltration, nanofiltration, and reverse osmosis. As you might guess, smaller pores filter out more impurities from the water.
The practical difference between ultrafiltration, nanofiltration, and reverse osmosis is the amount of material that's removed from the water. Imagine pouring water through a colander vs. cheese cloth. The colander will filter out large substances, while the cheese cloth will filter out the big stuff plus some smaller materials, too.
If ultrafiltration and nanofiltration are the colander, then reverse osmosis is more like cheesecloth. The tiny pores in a reverse osmosis membrane effectively filter out nearly all particles.
A more scientific explanation of the differences across these methods is shown in the table below.
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