Model: SHD01-H-02

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1.Low Smoke ZERO Halogen LSZH Compound

Low Smoke ZERO Halogen Compound is based on polyolefin and contains special halogen-free flame retardants and smoke suppressants, which are processed by precise mixing with unique formulas.

 

2.Features:

- This flame retardant system has excellent zero halogen flame retardancy.

- When the plastic cable sheathing structure is designed reasonably, it can pass the A/B/C type combustion test and meet the light transmittance requirements.

- When burning, no halogen acid gas is released, the amount of toxic and corrosive gas is tiny, and the smoke concentration is shallow.

- This zero halogen flame retardant compound has excellent resistance to environmental stress cracking and good extrusion processability.

- We can also provide anti-termite, anti-rodent, and UV-resistant properties according to customer requirements.

 

3. Implementing standards: GB/T-, YD/T, IEC-359-

 

4. Uses

The SHD01-H-02 series of Low Smoke ZERO Halogen Compound not only have excellent low-smoke halogen-free flame retardant properties, but also have excellent extrusion processing properties. It can be extruded on an ordinary PVC extruder. As long as the cooling device is normal, the extrusion processing speed can be accelerated. The performance of the cable compound is better than similar products. The cable compound is suitable for occasions with high flame retardant requirements and low secondary hazards, such as: subways, ships, power stations, high -rise buildings, program-controlled switch rooms, computer rooms and various crowded public places. Suitable for optical cable and wire core working temperature 90 &#; low smoke halogen free flame retardant cable sheath. The cable compound is guaranteed to pass various beam burning tests and light transmittance tests.

 

5. Extrusion process

The drying temperature is 65°C and the drying time is at least 2 hours. It is advisable for the hot material to enter the extruder. It can be extruded by L/D18-25 extruder. When the screw compression is relatively low, the output is larger. Each zone of the extruder must have a cooling control system, and the melt temperature should not exceed 180 °C. Since the difference between the actual temperature of the melt and the indicated value of the temperature control table varies with the type of extruder, each user should select a suitable temperature according to the specific conditions of the extruder used. The following temperatures can be used as a reference for commissioning:

barrel position

zone 1

zone 2

zone 3

zone 4

nose and mode

Temperature(&#;)

125±5

135±5

145±5

155±5

160±5

Note: If the aluminum-plastic composite inner bag&#;damp proof fails, it should be dried before use. The drying temperature should be 65&#; and the drying time should be at least 2 hours. It is better for hot material to enter and leave the extruder.The machine head can be without a filter screen, or a filter screen below 60 mesh can be used; the mold can be extruded or tube type.

 

6. Packaging, transportation and storage

Packing: N.W: 25kg/kg bags with inner bag of aluminum-plastic composite vacuum moisture-proof bag and outer packing being made of kraft paper composite bag or woven bag.

Transportation and storage: It should not be exposed to the sun and rain during transport. It should be stored in a clean, cool, dry and ventilated warehouse. It should be handled with care.

 

7. Shelf life : 6 months

 

8. Physical and mechanical properties

Project name

Units

SHD01-H-02

Normal value

Typical Value

Density

g/cm³

&#;&#;

1.45

Hardness (Shore D1S)

 

&#;&#;

58

Tensile strength

MPa

&#;10.0

12.5

Elongation at break

%

&#;160

215

Heat aging in air oven (100&#;×168h)

 

 

 

Aging Tensile Strength

MPa

&#;10.0

11.3

Rate of change in tensile strength

%

Max ±30

+15

Elongation at break after aging

%

&#;120

175

Change rate of elongation at break

%

Max ±30

-9.5

Environmental stress cracking resistance

h

&#;96

pass

Heat stress cracking

h

&#;96

pass

Low temperature impact embrittlement temperature

&#;

-25&#;

pass

Volume resistivity at 20&#;

Ω.m

&#;1.0×

3.1×

Dielectric Strength

MV/m

&#;18

37

Oxygen Index

 

&#;30

38.5

Smoke density is flaming

 

&#;100

84

Flameless

 

&#;350

340

Halogen acid gas release amount

mg/g

&#;5

With competitive price and timely delivery, SUNUA sincerely hope to be your supplier and partner.

0

PH value

 

&#;4.3

6.0

Conductivity

µS/mm

&#;10

0.3

Toxicity index

 

&#;5

0.5

 

For more information about Low Smoke Zero Halogen Materials, click on the link to contact our product specialists.

Produced by:

IEEE

Globalspec Media Solutions

Low smoke zero halogen compounds not only deliver greater fire protection performance, they have been constantly evolving so that the number of applications and performance are increasing, while relative cost is beginning to decline.

A number of high-profile fires over the past several decades have served to alert just how dangerous plastics can be when burned. In the King&#;s Cross fire in the late s, for example, 32 people died in a London underground subway from the toxic fumes. That one incident prompted the U.K. to initiate more stringent standards to prevent halogen-related deaths, even though at that time the cable would not be as flame retardant as PVC jacketed cable.

Figure 1: A new approach to cabling &#; using low smoke zero halogen wire and cable &#; is proven to produce less smoke, giving people more time to escape a fire when time is of the essence. (Source: Adobe Stock)

In addition to fatal fires, the sheer volume of cable that exists today adds fuel to residential, commercial and industrial settings. In response, materials with a high resistance to fire were developed with little performance penalty. Low smoke zero halogen (LSZH) compounds not only deliver greater fire protection performance, they have been constantly evolving so that the number of applications and performance are increasing, while relative cost is beginning to decline.

Before looking at the particulars of LSZH wire and cable compared with the use of PVC-based products, it&#;s important to wade through the plethora of terms involved.

Acronyms, Common Terms and Misnomers

The industry is quite familiar with such communications cable terms as CM, PVC and LSZH. There are, however, endless terms that mean the same thing, almost the same thing and definitions not even in the same ballpark. Here, then, is a list that might help:

• CM

  indicates that the cable is National Electrical Code (

  NEC

  or

  NFPA

  70) compliant.

  CM

  designates use for low voltage communications circuits restricted to one floor.

• CMR

  , also known as riser-rated cable, is used to prevent fires spreading between vertical installations, when cables are used between floors through risers or vertical shafts.

• CMP

  , also known as plenum-rated cable, is able to restrict flame propagation to five feet or less, while also limiting the amount of smoke during a fire. It is often installed above suspended ceilings so that air passes through.

• PVC

  (polyvinyl chloride) is most often associated with

  CM

  and

  CMR

  -rated cable. Examine the extensive features and characteristics of

  PVC

  throughout this paper.

• FEP

  (fluorinated ethylene polymer) is most often associated with

  CMP

  cable.

  CMP

  cable may use a low smoke

  PVC

  jacket.

• LSZH

  , 

  LSOH

  and 

  LSNH

  indicate by the letters

  ZH

  , 0H,

  OH

  ,

  HF

  ,

  NC

  and

  NH

  that the materials used in producing the cable are free of halogen.

  LS

  signifies that low smoke materials are used.
• The 

  FR

   in

  FRLS

  and other acronyms indicates the materials improve reaction to fire (low fire). Low-smoke, low-fire and zero-halogen cables must meet

  IEC

  standards.

Misnomers? It is often thought that cable designated LSF (low smoke and fume) is the same as LSHF (low smoke halogen free). Low smoke and fume is obviously not as stringent a classification as is LSHF or LSZH, to be consistent in this white paper.

Clearly, when making such a critical decision, engineers must know what it is they&#;re choosing from, and that they&#;re getting what they need and also what they are paying for.

The Growing Importance of

LSZH

Low smoke zero halogen cable insulation and jacket have no fluorine, chlorine, bromine, iodine or astatine, so they do not emit toxic or corrosive fumes and create minimal smoke when fire is present. LSZH cables feature a flame-resistant jacket that doesn&#;t emit toxic fumes even if burned.

Figure 2: A patch cable. (Source: Quabbin Wire

&

Cable)

LSZH cables also feature:

• Non-propagation of fire and flame
• Less dense smoke emission

• IEC

  standards compliance
• Flame retardant

â&#;&#;Given the absence of PVC, when burned, LSZH cable produces small amounts of light grey smoke and minute levels of hydrochloric acid (HCl), increasing the chance of escape during a fire. Sheath and conductor insulation of the cable can be made from polyethylene, containing little chlorine, so that HCl is not an issue.

A Low Smoke Halogen Free (LSHF) certification from UL indicates that the combustible materials in use are halogen free and also comply with low smoke requirements when tested in accordance with IEC -2. To be designated zero-halogen, the material must have less than 0.2% of halogens by weight. Ensuring compliance involves UL testing, adherence to MIL-C-, acid gas testing to establish a pH level under 3, testing for halogen content, smoke release and acid-gas equivalence.

If LSZH has a downside in addition to a cost premium of approximately 30%, it is not as flexible as PVC and therefore more prone to jacket cracking during installation. Installation may require special lubrication to avoid damage, especially in cold environments. For that reason, it is generally not ideal for robotic or continuous flex applications. Advances in the underlying compound materials and processing continue to lessen some of these issues. ZHTPU is an example of a zero halogen material suitable for robotics.

The Up and Downside of

PVC

Polyvinyl chloride (PVC) has been the traditional go-to wiring and cable material for more than 60 years. While it has a long life, is inexpensive to make and features compounds and processes that have gradually improved over the years, it also has some negatives.

When PVC burns, it produces chemicals and dense black smoke, rapidly reducing visibility. Within approximately 10 minutes, visibility is down by 50% and within a half hour, 90%. The result is a dramatic decrease in a person&#;s ability to escape. However, visibility isn&#;t the only problem. A burning PVC cable also emits hydrochloric acid and other toxic gases when it burns. Hydrogen chloride (HCl) can represent up to 30% of the emissions. When it is mixed with water, it forms hydrochloric acid, which is toxic as well as corrosive.

When HCl is inhaled, breathing becomes extremely difficult as the lining of the throat swells. If it comes in contact with eyes, it causes irritation all the way to permanent corneal damage. It also damages mucus membranes. Given these physical reactions combined with impeded visibility, it is easy to see why fatalities are high in building fires. In the King&#;s Cross Station fire, many died from smoke and fume inhalation.

Yet PVC, when not used in an area where there is a high level of humans, has its advantages, including:

• PVC

  s are inherently resistant to ignition, which may slow down the spread of a fire throughout the building.

  PVC

  compounds often include smoke suppression ingredients and additional flame-retardant properties.

• PVC

  is recyclable so that a high percentage is recycled back into wire and cable.

• PVC

  is produced using substantially less energy than alternative materials.

Common wire and cable insulation materials include PVC, cross-linked polyethylene (XLPE) and ethylene propylene rubber (EPR). Multiple chemical ingredients are added to provide performance, longevity, flexibility and ruggedness.

LSZH

vs.

PVC

Both LSZH and PVC cables feature excellent performance. Comparing them side by side, their differences become clear.

The advantage of halogenated flame retardants is that they are cost-effective and reduce the flammability of products without negatively affecting the processing properties of the polymers. Once heated, however, LSZH shines. PVC cable when burned emits toxic chemical fumes and acid. LSZH cable meets both health and safety standards.

Halogen-free wiring is still more complex and expensive to produce, uses more electricity and water in the process, and production is slower than PVC. In comparison, PVC is easier to process. It can be melted and made with a small amount of energy.

In an environment on fire, when visibility is reduced by up to 90% and with high HCl emissions, the difference between the two is even clearer. If the health and safety demands fire-proof cables, LSZH is worth the expense. If not, PVC cables are most likely the solution.

In the future, however, as the cost of LSZH comes closer to parity with PVC, and the attractiveness of being able to offer one cable globally becomes increasingly more important in a standard-centric world, LSZH will most likely begin to replace PVC across the board.

Applications

For most companies currently using LSZH cable, the application represents the deciding factor for the transition from PVC.

Halogen-free cable is intended for use in applications where insulation with low toxicity, low smoke generation and low corrosiveness is necessary, such as:

• Mass transit
• Datacenters
• Aviation
• Industrial environments
• Subways
• Buildings
• Nuclear/Military use
• Shipping
• Wherever human safety and protection of equipment is a primary goal
• In confined spaces with large amounts of cables near humans or electronics

While widespread use exists in Europe, the U.S. has lagged based on expense and performance concerns as well as complex building standards. Historically cable designs in Europe were often unable to pass testing standards prevalent in the U.S.

Figure 3: Data centers &#; with their enormous amount of cabling &#; are particularly susceptible to catastrophic fires. The adoption of

LSZH

cabling can make a world of difference in these environments. (Source: Adobe Stock)

Applications in cold environments are difficult with LSZH cables, as there is reduced flexibility of the cables based on high additive loading. One advantage is low friction, enabling a move toward jackets that do not require lubrication often used during cable pulls.

Modern data centers, laden with large amounts of cabling and enclosed spaces containing cooling systems, are beginning to move towards LSZH adoption. It is reasonable to expect this trend to continue as the technology&#;s popularity takes hold based on safety and its environmentally friendly designation.

Insurance companies are also specifying LSZH cable. Globalization of the cable design, often called &#;dual rated,&#; will simplify installation, training and logistics. The ability to cover both Europe and North America will be significant.

A Look at Evolving Global Standards

Globally, while European safety standards have concentrated primarily on low smoke and zero halogen (LSZH) cable as well as electrical requirements, standards in the U.S. have focused on fire resistant properties and propagation of flame resistance during fires. In North America, the onus is on meeting building codes where there are more stringent electrical requirements, as well as an emphasis on wet electrical properties.

Given that U.S. and European standards are, in effect, diametrically opposed, it is important for wire and cable suppliers and consumers to have a product that will address a wide range of requirements, while meeting global standards along the way.

In addition to a variation in standards, there is also substantial confusion regarding low smoke zero halogen cables and the materials involved. Part of the confusion surrounds the product itself, variations as to what LSZH means and the fact that although cable suppliers are likely attempting to offer the best product possible, self-certification and testing can be counterproductive. The standards themselves have led to confusion. Here is a recap ranging from earlier standards to the latest, for example, and it is apparent as to why variations in halogen content exist:

IEC -1&#;Test on gases evolved during combustion of materials from cables&#;Part 1: Determination of the halogen acid gas content

IEC -2&#;Test on gases evolved during combustion of materials from cables&#;Part 2: Determination of acidity (by pH measurement) and conductivity

The above standards fail to consider chlorine, bromine or fluorine content and use the titration and pH and conductivity methods, respectively, to test halogen content. IEC -2 describes recommended pH value performance values rather than mandating them.

In , the IEC developed the LSHF -1, -2 and -3 standard series, Electric Cables&#;Halogen Free, Low Smoke, Thermoplastic-Insulated and Sheathed Cables of Rated Voltages up to and including 450/750 V.

This standard prompted the UL to create two certification programs, a material recognition service that employs test methods from IEC -1/-2 and IEC -1/-2 under Subject Outline UL , Outline of Investigation for Acid Gas, Acidity and Conductivity of Combusted Material and Assessment of Halogens. Cables certified under UL&#;s Recognized Component program are published in UL&#;s Online Certifications Directory so that cable manufacturers globally can search for compliant halogen-free wire and cable materials.

UL created Halogen Free (HF) and Low Smoke Halogen Free (LSHF) optional certification marks for wire and cable, and the requisite testing to ensure compliance to the IEC series of standards covering such categories as communications cable, optical fiber, flexible cords, power and control tray cable (TC), and appliance wiring material (AWM). The markings indicate that the cable automatically meets other UL general certification requirements, and certifications are covered under UL&#;s Follow-Up Service (FUS) program for monitoring and testing.

There are additional standards that are not as comprehensive as the above-mentioned ones, only covering cable jackets, for example, rather than the complete cable construction.

Virtually all European installations are mandated to meet the latest IEC specification. In addition, there is high demand that new installations also meet IEC -3, representing a more stringent LSZH flammability specification.

Additional tests over and above those carried out on PVC/LSF variants include:

• EN

  -2-1, which stipulates that emissions of hydrochloric acid must not exceed 0.5%, and

• EN

  -2 that stipulates that during the burning process visibility must not be reduced by more than 40%.

BS EN -1 establishes testing covering permissible levels of acidity, conductivity and fluorine produced through the burning process for LSZH flexible cable.

In an Actual Fire

In a fire situation, many synthetic materials will burn. In most fires, PVC is only one of the culprits. In several documented cases involving the presence of PVC, however, the fires would not have occurred, spread rapidly or emitted gases and chemicals that were life threatening if PVC were not present.

There are four elements involved with the burning of PVC, including hydrochloric acid in the smoke, dioxin, the spread of the fire, and wire and cable insulation. When PVC is involved, the fatalities are due to smoke inhalation. Today, that means hydrochloric acid in the smoke, while in the past, when substantially less synthetics are used in the environment (including wire and cable), it would have meant carbon monoxide in the smoke. These synthetics include not only PVC, but also vinyl in tile, plastic in furniture and carpeting, etc. The tragedy, unfortunately, is that the environment rapidly becomes a virtual gas chamber, often in just a couple of minutes.

Summary

Halogens produce toxic and corrosive combustion byproducts. While on one hand they are flame retardant in nature, they emit toxic gases when burned and damage electronics. PVC will remain a viable solution for wire and cable well into the future, because of its versatile performance and cost effectiveness. In closed environments, however, LSZH continues to gain in popularity. Not only is it substantially safer to use where humans are working or living, compound formulation continues to dramatically improve LSZH, and standards now exist to ensure the product is compliant to today&#;s stringent testing and chemical requirements.

As the use of LSZH climbs, it is important to establish that what is being purchased is actually LSZH. The availability of testing and criteria established by the UL was needed to spur transition, moving from supplier self-certification to an important standard and clear and verifiable criteria. Still, there is substantial material on the market today that claims to be low-smoke but actually is not.

Quabbin Wire & Cable, for example, has an LSZH product available now that meets the flame and low smoke requirements and complies with IEC and IEC , but haven&#;t completed certification yet. Expectations are that a move toward LSZH will continue to gain traction as suppliers become UL compliant and its cost continues to decline.

_______________________________________

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