What are the properties of biaxially oriented polypropylene?

Orientation of polymers enhances many of their properties, particularly the mechanical, impact, barrier and optical properties. Biaxial orientation has the added advantage of allowing this enhancement in two directions, avoiding any weakness in the transverse direction. Biaxial orientation is particularly important in films, where it allows the production of thinner films having superior mechanical, optical and barrier properties and, if required, the ability to shrink when reheated. For example, shrink and barrier properties are particularly important in meat packaging, whereas good mechanical and optical properties and no shrinkage are desired in box overwrap applications of tape cassettes and CDs.

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Abstract

The double bubble tubular film (DBTF) process is a more economical way of producing biaxially oriented film, when compared to the tenter biaxially oriented film process. This film manufacturing technique has been widely used to produce biaxially oriented films because of good shrinkability and high physical properties. Recently, shrinkage film for this usage is required to have good stretchability and shrinkage strength. But the biaxial stretchability changes of polypropylenes and the reasons for such have not been reported upon systematically.

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In this report, the relationship between stretchability and material design of various polypropylenes (PP) for biaxially oriented film, which are most popular polymers, was investigated. Several different ethylene contents and melt flow indices (MI) of PP were examined. There was a correlation between MI, ethylene content and the stretchability of the DBTF. A random copolymer with MI 2 g/10 min and ethylene content 4.0 wt.% gave good stretchability. The most suitable composition distribution for stretching and the properties of biaxially oriented films were studied by using the temperature rising elution fractionation.

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